MATERIAL SAFETY DATA SHEET
Discontinued:
Date of Preparation: 12/18/2007
Page 1of 7
SECTION I - Product and Company Description

Product Name: Pit Cushion Patch Part A
Product Use: Isocyanate
Product Number: 12-250281-000A

Company: Brunswick
525 W. Laketon
Muskegon, MI 49443

Telephone #: 1/231/725-4972
Emergency #: 1/800/255-3924
CHEMTEL #: 1/800/255-3924
International CHEMTEL #:

SECTION II - Composition/Information on Ingredients
HAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Dicyclohexylmethane - 4, 4' -diisocyanate
Methylene Bisphenyl Isocyanate
Methylene Bisphenyl Isocyanate
Homologues of Methylene Bisphenyl Isocyanate		5124-30-1
101-68-8
26447-40-5
9016-87-9		5124-30-1
101-68-8
26447-40-5
9016-87-9		N 30.0
Y 4.0
Y 5.0
Y 5.0
NONHAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Non hazardous ingredientsProprietaryProprietaryN 56.0

This product contains a chemical reported to be a carcinogen or suspected carcinogen.
SECTION III - Hazards Identification

Overexposure may cause lung damage. Ingestion - May cause irritation in the mouth, stomach and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea. Primary route of entry - Eyes, skin and respiratory. Signs and symptoms of exposure - EYES - irritation. SKIN - irritation, redness, swelling, allergic skin reaction. RESPIRATORY TRACT - irritation, coughing, shortness of brethe, wheezing. Existing Conditions Aggravated By Exposure - Preexisting skin and eye disorders may be aggravated by exposure to this prodcut. Preexisiting skin or lung allergies may increase the chance of developing increased allergic symptoms from exposure to this product.
12-250281-000A
Pit Cushion Patch Part A
MATERIAL SAFETY DATA SHEET
Page 2 of 7
SECTION IV - First Aid Measures

EYE CONTACT: Flush with lukewarm water for 15 minutes. Contact physician.
SKIN CONTACT: Do not remove with solvent. Use waterless hand cleaner followed by soap and water. Remove and clean contaminated clothing.
INHALATION: Remove exposed individual to fresh air. Restore breathing, if necessary. Get medical attention.
INGESTION: Rinse mouth. Call a physician or Poison Control Center immediately. DO NOT induce vomiting unless advised by a physician.
SECTION V - Fire-Fighting Measures

EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam
SPECIAL RISKS: Vapors heavier than air. Development of hazardous combustion gases or vapors possible in the event of fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: Fire Fighters should use self-contained breathing apparatus with face piece.
OTHER INFORMATION: Keep away from sources of ignition. Prevent fire-fighting water from entering surface water or groundwater. Cool Container with spray water from a safe distance. Never use welding or cutting torch on or near container (even empty) because product may ignite explosively.
SECTION VI - Accidental Release Measures

PERSON RELATED PRECAUTIONARY MEASURES: Avoid substance contact. Do not inhale vapors. Ensure fresh air supply in enclosed areas.
ENVIRONMENTAL PROTECTION MEASSURES: Do not allow to enter sewage system, surface or groundwater.
PROCEDURES FOR CLEANING/ABSOPRTION: Use inert absorbent material to take up spilled material. Place in appropriate container until proper disposal method is determined.
SECTION VII - Handling And Storage

NOTES FOR PREVENTION OF FIRE AND EXPLOSION: Keep away from sources of ignition. Use and store this product with adequate ventilation.
NOTES FOR SAFE HANDLING: Avoid generation of vapors. Do not inhale vapors.
STORAGE: Store in well-ventilated area between 40 F (4C) and 100 F (38C). Store away from heat and sources of ignition.
Brunswick takes no responsibility for determining what measures are required for personal protection in any specific application. The general information given should be used with discretion.


12-250281-000A
Pit Cushion Patch Part A
MATERIAL SAFETY DATA SHEET
Page 3 of 7
SECTION VIII - Exposure Controls/Personal Protection

Hazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Dicyclohexylmethane - 4, 4' -diisocyanate
Methylene Bisphenyl Isocyanate
Methylene Bisphenyl Isocyanate
Homologues of Methylene Bisphenyl Isocyanate		0.005 ppm
0.005 ppm
0.005 ppm
0.051 mg/m3		0.005 ppm
Not established
0.02 ppm
0.2 mg/m3
NonHazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Non hazardous ingredientsNot establishedNot established

PERSONAL PROTECTIVE EQUIPMENT: Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the substances being handled. The resistance of the protective clothing should be ascertained from the respective supplier.

RESPIRATORY PROTECTION: Required when vapors are generated.

EYE PROTECTION: Splash goggles.

HAND PROTECTION: Chemical resistant gloves and skin cream.

INDUSTRIAL HYGIENE: Immediately change any contaminated clothing. Apply skin protective barrier cream. Wash hands and face after handling product. Do not inhale vapors.
SECTION IX - Physical and Chemical Properties

Physical State: Brown liquid
Odor: Aromatic
pH: N/A
Viscosity:
Lowest Flashpoint: >275 F (135 C) Boiling Point: > 300 F. (> 148.9 C)
Explosion Level: Lower - N/A Upper - N/A
Vapor Pressure: 0.2
Vapor Density: (Air = 1) 3.6
Weight Per Gallon: lbs./gal.
Solubility: Soluble in water


12-250281-000A
Pit Cushion Patch Part A
MATERIAL SAFETY DATA SHEET
Page 4 of 7
SECTION X - Stability and Reactivity

Conditions to be avoided: High temeperature, open flame.
Substances to be avoided: Strong oxidizing agents
Hazardous decomposition products: N/I
Further information: Hazardous polymerization: Exothermic
SECTION XI - Toxicological Information

Acute Toxicity:
Testing has not been performed on this product.

Specific symptoms in animal studies:
Subacute to chronic toxicity:
Bacterial mutagenicity:
Further toxicological information:

Further Data:



12-250281-000A
Pit Cushion Patch Part A
MATERIAL SAFETY DATA SHEET
Page 5 of 7
SECTION XII - Ecological Information

Biologic degradation:

Ecotoxic effects:
Biological effects:
Fish toxicity:
Daphnia toxicity:
Maximum permissible toxic concentration:
Algeal toxicity:
Bacterial toxicity:
Protozoa:
Further ecological data: No specific studies have been conducted on the ecotoxicity or environmental fate of this material; however, commonly available data on the ecotoxicity and environmental fate of certain constituents of this material indicate that uncontrolled release to soil, groundwater, or surface waters could entail acute and/or chronic ecological effects, depending on the quantity and concentration of such releases. Releases of volatile components to the atmospere are not believed to entail significant ecological consequences provided such releases are within the exposure levels set forth in section 8. Accordingly, all appropriate measures should be taken to avoid uncontrolled releases of this material into the environment, and any spills or other uncontrolled releases which may occur should be contained and cleaned up immediately in accordance with section 6.
SECTION XIII - Disposal Considerations

Product: Chemicals must be disposed of in accordance with national and local regulations.

Packaging: Packaging must be disposed of in compliance with national and local regulations.


12-250281-000A
Pit Cushion Patch Part A
MATERIAL SAFETY DATA SHEET
Page 6 of 7
SECTION XIV - Transportation Information

Package Desc:
Weight:
Dimensions:
Freeze/Thaw stable:
Flashpoint: >275 F (135 C) Boiling Point: > 300 F. (> 148.9 C)

Land transport:
Classification: Not regulated
Name:


Transport by sea: Not regulated
Classification:
EMS
MFAG
Name

Transport by air: Not regulated
Classification:
Name:
Packaging Instructions:

The transport regulations are cited according to international regulations and in the form applicable in the United States. Possible deviations in other counties are not considered.
THIS TRANSPORT DATA APPLIES TO THE ENTIRE PACKAGE.
SECTION XV - Regulatory Information

Labeling according to Land Transport:
Hazard: Not regulated
Package:
Other: Orientation Arrows

Labeling according to Sea Transport:
Hazard: Not regulated
Package:
Other: Orientation arrows

Labeling according to Air Transport
Hazard: Not regulated
Package:
Other: Orientation arrows


12-250281-000A
Pit Cushion Patch Part A
MATERIAL SAFETY DATA SHEET
Page 7 of 7
SECTION XVI - Other Information

Hazard Classification
H - 3 F - 1 R - 0

The information contained herein is information received from our raw material suppliers and other sources and is believed to be reliable. This data is not to be taken as warranty or representation for which Brunswick assumes legal responsibility.

This Safety Data Sheet complies with EC Commission Directive 2001/58/EC of July 2001