MATERIAL SAFETY DATA SHEET
Discontinued:
Date of Preparation: 01/24/2007
Page 1of 7
SECTION I - Product and Company Description

Product Name: Dura-Thon One Step GID
Product Use: Urethane Dispersion
Product Number: 1170095

Company: DBA Products Company Inc.
525 W. Laketon
Muskegon, Michigan 49441

Telephone #: 1/231/725-4972
Emergency #: 1/800/255-3924
CHEMTEL #: 1/800/255-3924
International CHEMTEL #: 1/813/248-0585

SECTION II - Composition/Information on Ingredients
HAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Polyurethane Prepolymer
Xylene
Ethyl Benzene
Toluene		TSRNHM2801
1330-20-7
100-41-4
108-88-3		N 25.5
Y 20.0
Y 40.0
Y 1.0
NONHAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Diphenylmethane-4, 4 Diisocyanate
1, 1 Methylenebisisocyanate
Pigment		101-68-8
26447-40-5
Proprietary		N 9.0
N 31.0
N .5

This product contains a chemical reported to be a carcinogen or suspected carcinogen.
SECTION III - Hazards Identification

EFFECTS OF SHORT TERM OVEREXPOSURE; Swallowing: May be fatal if swallowed. Can cause gastrointestinal irritation, nausea, and vomiting. Aspiration of material into lung may cause chemical pneumonitis which can be fatal. Inhalation: WARNING: vapor and spray mist harmful. Overexposure may cause lung irritation and allergic respiratory reaction. Effects may be permanent. May cause respiratory sensitization (potential for allergic reaction). May cause nose or throat irritation. High concentration may cause acute central nervous system depression characterized by headaches, dizziness, nausea, and confusion. Eye: May cause severe eye irritation. Skin: Primary skin irritant. May cause skin sensitization (allergic reaction). May cause severe skin irritation. EFFECTS OF REPEATED OVEREXPOSURE: Overexposure to xylene may cause injury to the liver, kidneys, and blood. Repeated exposure to isocyanates may result in respiratory sensitization for some people. Respiratory sensitivity results in asthma-like symptoms on subsequent exposure at concentrations even below the TLV. Reports have associated prolonged and repeated occupational damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH: None currently known
1170095
Dura-Thon One Step GID
MATERIAL SAFETY DATA SHEET
Page 2 of 7
SECTION IV - First Aid Measures

EYE CONTACT: Flush with lukewarm water for 15 minutes. Contact physician.
SKIN CONTACT: Do not remove with solvent. Use waterless hand cleaner followed by soap and water. Remove and clean contaminated clothing.
INHALATION: Remove exposed individual to fresh air. Restore breathing, if necessary. Get medical attention.
INGESTION: Rinse mouth. Call a physician or Poison Control Center immediately. DO NOT induce vomiting unless advised by a physician.
SECTION V - Fire-Fighting Measures

EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam
SPECIAL RISKS: Vapors heavier than air. Development of hazardous combustion gases or vapors possible in the event of fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: Fire Fighters should use self-contained breathing apparatus with face piece.
OTHER INFORMATION: Keep away from sources of ignition. Prevent fire-fighting water from entering surface water or groundwater. Cool Container with spray water from a safe distance. Never use welding or cutting torch on or near container (even empty) because product may ignite explosively.
SECTION VI - Accidental Release Measures

PERSON RELATED PRECAUTIONARY MEASURES: Avoid substance contact. Do not inhale vapors. Ensure fresh air supply in enclosed areas.
ENVIRONMENTAL PROTECTION MEASSURES: Do not allow to enter sewage system, surface or groundwater.
PROCEDURES FOR CLEANING/ABSOPRTION: Use inert absorbent material to take up spilled material. Place in appropriate container until proper disposal method is determined.
SECTION VII - Handling And Storage

NOTES FOR PREVENTION OF FIRE AND EXPLOSION: Keep away from sources of ignition. Use and store this product with adequate ventilation.
NOTES FOR SAFE HANDLING: Avoid generation of vapors. Do not inhale vapors.
STORAGE: Store in well-ventilated area between 40 F (4C) and 100 F (38C). Store away from heat and sources of ignition.
Brunswick takes no responsibility for determining what measures are required for personal protection in any specific application. The general information given should be used with discretion.


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Dura-Thon One Step GID
MATERIAL SAFETY DATA SHEET
Page 3 of 7
SECTION VIII - Exposure Controls/Personal Protection

Hazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Polyurethane Prepolymer
Xylene
Ethyl Benzene
Toluene		Not established
100 ppm mg
100 ppm mg
50 ppm mg		Not established
100 ppm mg
100 ppm mg
50 ppm mg
NonHazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Diphenylmethane-4, 4 Diisocyanate
1, 1 Methylenebisisocyanate
Pigment		.05 ppm mg
.05 ppm mg
10 mg/M3		.05 ppm mg
.05 ppm mg
10 mg/M3

PERSONAL PROTECTIVE EQUIPMENT: Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the substances being handled. The resistance of the protective clothing should be ascertained from the respective supplier.

RESPIRATORY PROTECTION: Required when vapors are generated.

EYE PROTECTION: Splash goggles.

HAND PROTECTION: Chemical resistant gloves and skin cream.

INDUSTRIAL HYGIENE: Immediately change any contaminated clothing. Apply skin protective barrier cream. Wash hands and face after handling product. Do not inhale vapors.
SECTION IX - Physical and Chemical Properties

Physical State: Liquid
Odor: Solvent
pH:
Viscosity: 30-60 cps measured at 25°C
Lowest Flashpoint: 72 ° F (22 C).
Explosion Level: Lower - Upper -
Vapor Pressure:
Vapor Density: (Air = 1) Heavier than air
Weight Per Gallon: 8.0 lbs./gal.
Solubility:


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Dura-Thon One Step GID
MATERIAL SAFETY DATA SHEET
Page 4 of 7
SECTION X - Stability and Reactivity

Conditions to be avoided: Avoid excessive heat (>115 F (46 C) and sources of ignition
Substances to be avoided: Strong acids and alkaline materials
Hazardous decomposition products: Burning, including when heated by welding or cutting, will produce smoke, carbon monoxide and carbon dioxide. In addition, oxides of nitrogen, may be generated. The reaction of isocyanates with water may produce carbon dioxide gas which may result in container pressurization.
Further information:
SECTION XI - Toxicological Information

Acute Toxicity:
NA

Specific symptoms in animal studies: NA
Subacute to chronic toxicity: NA
Bacterial mutagenicity: NA
Further toxicological information: NA

Further Data: NA



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Dura-Thon One Step GID
MATERIAL SAFETY DATA SHEET
Page 5 of 7
SECTION XII - Ecological Information

Biologic degradation: NA

Ecotoxic effects: NA
Biological effects: NA
Fish toxicity: NA
Daphnia toxicity: NA
Maximum permissible toxic concentration: NA
Algeal toxicity: NA
Bacterial toxicity: NA
Protozoa: NA
Further ecological data: NA
SECTION XIII - Disposal Considerations

Product: Chemicals must be disposed of in accordance with national and local regulations.

Packaging: Packaging must be disposed of in compliance with national and local regulations.


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Dura-Thon One Step GID
MATERIAL SAFETY DATA SHEET
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SECTION XIV - Transportation Information

Package Desc: 1 Steel Drum x 18.92 Liters (5 Gallons)
Weight: 45#
Dimensions: 11x11x14 = .981
Freeze/Thaw stable: N/A
Flashpoint: 72 ° F (22 C).

Land transport:
Classification: UN1866, Resin Solution, 3, II
Name:

Transport by sea:
Classification: UN1866, Resin Solution, 3, II
EMS F-E, S-E
MFAG
Name

Transport by air: Cargo Aircraft Only
Classification: UN1866, Resin Solution, 3, II
Name:
Packaging Instructions: 307 - Cargo Aircraft Only

The transport regulations are cited according to international regulations and in the form applicable in the United States. Possible deviations in other counties are not considered.
THIS TRANSPORT DATA APPLIES TO THE ENTIRE PACKAGE.
SECTION XV - Regulatory Information

Labeling according to Land Transport:
Hazard: Flammable Liquid
Package: Resin Solution, UN1866
Other: Orientation Arrows

Labeling according to Sea Transport:
Hazard: Flammable Liquid
Package: Resin Solution, UN1866
Other: Orientation Arrows

Labeling according to Air Transport
Hazard: Flammable Liquid
Package: Resin Solution, UN1866
Other: Orientation Arrows - Cargo Aircraft Only


1170095
Dura-Thon One Step GID
MATERIAL SAFETY DATA SHEET
Page 7 of 7
SECTION XVI - Other Information

H.M.I.S. Ratings: Health: 3 Flammability: 3 Reactivity: 1

All ingredients in his product are listed on the US TSCA Inventory.

INGREDIENT CAS NO. DETAIL INVENTORY LIST INFORMATION

Polyurethane Prepolymer TSRNHM2801 No information available.

Xylene 1330-20-7 TSCA (8a PAIR)
DSL

Ethyl Benzene 100-41-4 TSCA (4a)
TSCA (8a PAIR)
TSCA (8d)
DSL

DETAIL INVENTORY LIST DESCRIPTION

TSCA
Toxic Substance Control Act
4a
TSCA 4a
8a PAIR
Preliminary Assessment Information Rules
8d
Health and Safety Reporting Rules
DSL
Canadian Domestic Substance List

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
The use of a NIOSH/MSHA approved, TC19C, air-supplied breathing apparatus may be required. Consult with a qualified occupational health and / or safety professional. Keep spectators away. Eliminate all ignition sources (flames, hot surfaces, and sources of electrical, static or frictional sparks). dike and contain spill with inert material (e.g. sand, earth). Transfer liquids to covered metal containers for recovery or disposal, or remove with inert absorbent. Use only non-sparking tools Place absorbent diking materials in covered metal containers for disposal. Prevent contamination of sewers streams, and groundwater with spilled material or used absorbent.

Waste Disposal: Disposal in accordance with federal, state, and local regulations.

RCRA classification: This product, if discarded directly, would be classified a hazardous waste based on its ignitability characteristic, i.e. has a flash point of 140 deg. F. (60 deg. C) or less. The RCRA classification would be D001.

HANDLING AND STORAGE:
Do not store above 115 deg. F. 946 deg. C) store large quantities in compliance with OSHA 29 CFR19103.106
OTHER PRECAUTIONS: Do not take internally. Close container after each use. This product should not be used by persons who have had chronic (long-term) breathing problems or reactions to isocyanates. Do not breath vapor spray or mist. do not get in eyes, skin, or clothing. Wash thoroughly after handling. Keep away from heat sparks or flame. Use only with adequate ventilation. Wash hands and face thoroughly before eating or drinking. Empty containers must not be washed and re-used for any purpose. Containers should be grounded and bonded to the receiving container. Do not weld, braze, or cut on empty container. Never use pressure to empty. Drum is not a pressure vessel.

EXPOSURE CONTROLS:

Respiratory Protection: Proper selection of respiratory protection depends upon many factors including duration/level of exposure and conditions of use. In general exposure to organic chemicals such as those contained in this product may not require the use of respiratory protection if used in well ventilated areas. In restricted ventilation areas a NIOSH approved chemical cartridge respirator may be required. Under certain conditions, such as spraying, a mechanical prefilter may also be required. In confined areas use a NIOSH/MSHA approved air supplied respirator.

Ventilation: Provide general dilution and local exhaust ventilation in sufficient volume and pattern to keep concentrations of hazardous ingredients below the lowest exposure limit stated. Remove decomposition products that are generated when welding, cutting, or brazing objects coated with this product. Refer to "industrial Ventilation - A Manual of Recommended Practice" ACGIH.

HAND PROTECTION: Wear appropriate impermeable gloves.

EYE PROTECTION: Wear safety glasses meeting the specification of ANSI Z87.1 where no contact with the eye is anticipated. Chemical safety goggles meeting the specification of ANSI Z87.1 should be worn whenever there is a possibility of splashing or other contact with the eyes.

OTHER PROTECTIVE EQUIPMENT: Eyewash facility, safety shower. As required to prevent skin contact.

The information contained herein is information received from our raw material suppliers and other sources and is believed to be reliable. This data is not to be taken as warranty or representation for which Brunswick assumes legal responsibility.

This Safety Data Sheet complies with EC Commission Directive 2001/58/EC of July 2001