MATERIAL SAFETY DATA SHEET
Discontinued:
Date of Preparation: 10/11/2007
Page 1of 7
SECTION I - Product and Company Description

Product Name: 321 Pro-Plug Hardener
Product Use: Epoxy Hardener
Product Number: 160321HO

Company: DBA Products Company Inc.
525 W. Laketon
Muskegon, Michigan 49441

Telephone #: 1/231/725-4972
Emergency #: 1/800/255-3924
CHEMTEL #: 1/800/255-3924
International CHEMTEL #: 1/813/248-0585

SECTION II - Composition/Information on Ingredients
HAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Proprietary Curing Agent
Proprietary Polymer
Diethylenetriamine
Proprietary Additive
Polyamines		Proprietary
Proprietary
000111-40-0
Proprietary
Proprietary		Y 28.0
N 35.0
Y 6.0
Y 5.0
Y 26.0
NONHAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.

This product contains a chemical reported to be a carcinogen or suspected carcinogen.
SECTION III - Hazards Identification

Product EC Risk Phrases: R21/22, R34, R43 Product EC Safety Phrases: S (1/2), S15, S 24/25. S27/28, S36/37/39 Product EC Labels Required: C H.M.I.S. Ratings: Estimated Health: 3 Flammability: 1 Reactivity: 0 NFPA Ratings: Estimated: Health: 3 Flammability: 1 Reactivity: 0 Other: 0 This product is a mixture containing numerous items requiring different labels, warnings, risk phrases and safety phrases. The product ratings are interpreted from the information presented by the MSDS Sheets of raw materials. The actual product information could vary from what is presented. This information is presented in good faith as a best attempt to convey necessary information to the public and purchasers. WARNING STATEMENT: DANGER! Corrosive- causes eye and skin burns. Harmful or fatal if swallowed. Harmful if absorbed through the skin. Causes respiratory tract irritation and can cause damage. Aspiration hazard if swallowed - can enter the lungs and cause damage. POTENTIAL HEALTH EFFECTS: ACUTE: Eyes: Product may cause irritation, experienced as pain, with excess blinking and tear production, and seen as extreme redness and swelling of the eye and chemical burns to the eye. Sever eye damage may cause extreme blindness. Skin: Product may cause sever irritation with pain, severe excess redness and swelling with chemical burns, blister formation, and possible tissue destruction. Cyanosis. Inhalation: Vapors or mist, especially as generated from heating the material or as exposure in poorly ventilated areas or confined spaces, are irritating and cause nasal discharge, coughing, and discomfort in the nose and throat. Prolonged or repeated over exposure may result in lung damage. Ingestion: Product may cause burning of the mouth, throat, and stomach with abdominal and chest pain, nausea, vomiting, diarrhea, thirst, weakness, and collapse. Aspiration may occur during swallowing or vomiting, resulting in lung damage. Mild tachycardia. Numbness of the mouth and tongue; CNS depression; Incoordination; seizures. Sensitization: This product is not expected to be a human sensitizer based on data from the majority of raw material and product history. It does contain raw material that may cause sensitization. Chronic: Repeated skin contact may cause a persistent irritation or dermatitis. Repeated inhalation may cause lung damage. Repeated skin contact may aggravate an existing dermatitis (skin condition). Overexposure to vapor, dust, or mist may aggravate existing respiratory conditions, such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease.
160321HO
321 Pro-Plug Hardener
MATERIAL SAFETY DATA SHEET
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SECTION IV - First Aid Measures

EYE CONTACT: Flush with lukewarm water for 15 minutes. Contact physician.
SKIN CONTACT: Do not remove with solvent. Use waterless hand cleaner followed by soap and water. Remove and clean contaminated clothing.
INHALATION: Remove exposed individual to fresh air. Restore breathing, if necessary. Get medical attention.
INGESTION: Rinse mouth. Call a physician or Poison Control Center immediately. DO NOT induce vomiting unless advised by a physician.
SECTION V - Fire-Fighting Measures

EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam
SPECIAL RISKS: Vapors heavier than air. Development of hazardous combustion gases or vapors possible in the event of fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: Fire Fighters should use self-contained breathing apparatus with face piece.
OTHER INFORMATION: Keep away from sources of ignition. Prevent fire-fighting water from entering surface water or groundwater. Cool Container with spray water from a safe distance. Never use welding or cutting torch on or near container (even empty) because product may ignite explosively.
SECTION VI - Accidental Release Measures

PERSON RELATED PRECAUTIONARY MEASURES: Avoid substance contact. Do not inhale vapors. Ensure fresh air supply in enclosed areas.
ENVIRONMENTAL PROTECTION MEASSURES: Do not allow to enter sewage system, surface or groundwater.
PROCEDURES FOR CLEANING/ABSOPRTION: Use inert absorbent material to take up spilled material. Place in appropriate container until proper disposal method is determined.
SECTION VII - Handling And Storage

NOTES FOR PREVENTION OF FIRE AND EXPLOSION: Keep away from sources of ignition. Use and store this product with adequate ventilation.
NOTES FOR SAFE HANDLING: Avoid generation of vapors. Do not inhale vapors.
STORAGE: Store in well-ventilated area between 40 F (4C) and 100 F (38C). Store away from heat and sources of ignition.
Brunswick takes no responsibility for determining what measures are required for personal protection in any specific application. The general information given should be used with discretion.


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MATERIAL SAFETY DATA SHEET
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SECTION VIII - Exposure Controls/Personal Protection

Hazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Proprietary Curing Agent
Proprietary Polymer
Diethylenetriamine
Proprietary Additive
Polyamines		Not established
Not established
Not established
Not established
Not established		Not established
Not established
Not established
Not established
Not established
NonHazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM

PERSONAL PROTECTIVE EQUIPMENT: Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the substances being handled. The resistance of the protective clothing should be ascertained from the respective supplier.

RESPIRATORY PROTECTION: Required when vapors are generated.

EYE PROTECTION: Splash goggles.

HAND PROTECTION: Chemical resistant gloves and skin cream.

INDUSTRIAL HYGIENE: Immediately change any contaminated clothing. Apply skin protective barrier cream. Wash hands and face after handling product. Do not inhale vapors.
SECTION IX - Physical and Chemical Properties

Physical State: Light yellow, oily transparent solution.
Odor: Amine odor
pH:
Viscosity:
Lowest Flashpoint: >225 ° F (107 C).
Explosion Level: Lower - Upper -
Vapor Pressure: < 1 mm Hg
Vapor Density: (Air = 1) NA
Weight Per Gallon: lbs./gal.
Solubility:


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MATERIAL SAFETY DATA SHEET
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SECTION X - Stability and Reactivity

Conditions to be avoided: High heat, strong oxidizers, acids, chlorinated hydrocarbons. Product will absorb CO2 from the air. Product may react violently with acids
Substances to be avoided:
Hazardous decomposition products: Fumes, carbon dioxide, carbon monoxide, acrid smoke, phenolics, and aldehydes.
Further information: Stability: Stable. Can auto ignite with air at approximately 675 F.
Hazardous Polymerization: Will auto-polymerize at very high temperatures.
SECTION XI - Toxicological Information

Acute Toxicity:


Specific symptoms in animal studies:
Subacute to chronic toxicity:
Bacterial mutagenicity:
Further toxicological information:

Further Data: Product has low acute oral toxicity. Chronic effects could include skin sensitization and lung irritation. No known carcinogenicity



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MATERIAL SAFETY DATA SHEET
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SECTION XII - Ecological Information

Biologic degradation: Based on information for diethylenetriamine, material has shown potential to biodegrade

Ecotoxic effects:
Biological effects:
Fish toxicity: Material is slightly toxic to aquatic organisms on an acute basis.
Daphnia toxicity:
Maximum permissible toxic concentration:
Algeal toxicity:
Bacterial toxicity:
Protozoa:
Further ecological data: OTHER: Generally not determined. Quantities involved in standard packaging suggest negligible impact probable. Bioconcentration: Based on information for diethylenetriamine, bioconcentration potential is low ( less than 100 or LOG KOW less than 3). Expected to be relatively immobile in soil (KOC greater than 5000).
Exotoxicity: Material is slightly toxic to aquatic organisms on an acute basis.
SECTION XIII - Disposal Considerations

Product: Chemicals must be disposed of in accordance with national and local regulations.

Packaging: Packaging must be disposed of in compliance with national and local regulations.


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MATERIAL SAFETY DATA SHEET
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SECTION XIV - Transportation Information

Package Desc:
Weight:
Dimensions:
Freeze/Thaw stable:
Flashpoint: >225 ° F (107 C).

Land transport:
Classification: UN3267, Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amine ), 8, III
Name:

Transport by sea:
Classification: UN3267, Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amine ), 8, III, Marine Pollutant (Polyamines)
EMS F-A, S-B
MFAG
Name

Transport by air:
Classification: UN3267, Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amine ), 8, III
Name:
Packaging Instructions:

The transport regulations are cited according to international regulations and in the form applicable in the United States. Possible deviations in other counties are not considered.
THIS TRANSPORT DATA APPLIES TO THE ENTIRE PACKAGE.
SECTION XV - Regulatory Information

Labeling according to Land Transport:
Hazard: Corrosive Liquid
Package: Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amine ), UN3267
Other: Orientation Arrows

Labeling according to Sea Transport:
Hazard: Corrosive Liquid
Package: Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amine ), UN3267
Other: Orientation Arrows - Marine Pollutant

Labeling according to Air Transport
Hazard: Corrosive Liquid
Package: Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amine ), UN3267
Other: Orientation Arrows


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MATERIAL SAFETY DATA SHEET
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SECTION XVI - Other Information

ACCIDENTAL RELEASE MEASURES: Wear protective equipment. Stop leak at its source; dike area; prevent material from entering waterway; prevent contact with strong oxidizers or acids; pump material to reclaim material; use absorbent on remaining material; and, shovel into disposal container. Use explosion proof equipment and non-sparking tools.

HANDLING AND STORAGE:
Handling: Do not wear contaminated clothing. Wash prior to eating, drinking, smoking, or use of restroom and when leaving work. Heating of non-vented container may cause container to rupture. Do not dispose of material or empty container into the environment. Avoid heat, sparks or static electricity. Use of explosion proof equipment and non-sparking tools.
Storage: Do not store near heat or open flame. Store at ambient temperatures. Do not allow freezing or overheating. If overheating occurs, be sure to shake well prior to usage.
INCOMPATIBLE MATERIAL: Strong oxidizers and reducers.
Ventilation: Local exhaust, unless heating to vapor or mist. Avoid breathing of mists or fumes

EXPOSURE CONTROLS/PERSONAL PROTECTION:
Respiratory Protection: Avoid prolonged or repeated breathing of vapors.
Protective Clothing: Avoid contact with eyes. Wear chemical goggles if splash or contact possible. Wear chemical resistant gloves and other clothing or vapor masks as required to minimize contact.

DISPOSAL CONSIDERATIONS:
Dispose of product by incineration in an approved chemical waste handling facility. Material once polymerized with hardener becomes relatively inert solid. Avoid landfilling of liquids. Since emptied container will contain residue from product, all labeled hazard precautions must be observed. If this material becomes a waste, it would not be a hazardous waste by RCRA criteria (40 CFR 261). Place an appropriate disposal facility in compliance with local regulations.

SARA TITLE III:
Section 302/304 Extremely Hazardous Substances: None Known

Section 311 Hazardous Categorization: Acute: X Chronic: Fire: Reactive:

Section 313 Toxic Chemical: None Known

CERCLA 102 (a)/ DOT Hazardous Substances: None known

TSCA: Class D, Div 1, Subdiv B: Toxic Class Class E: Corrosive

EINICS Inventory Status: Not determined

State Right-to-Know Regulations: None known

TSCA Inventory of Chemical Substances lists some or all of this product's components: None known

SARA 311/312 Hazard Categories: None known.

SARA 313 Toxic Chemicals: None known

CERCLA Hazardous Substances: None known.

Canadian Regulations:
D1B - Material is toxic with short exposure and moderate dose.
D2A - Material is teratogenic, embryotoxic, or fetotoxic
D2B - Skin sensitizer.
E - Corrosive to metal or skin

Hazardous Products Act Information: This product contains the following ingredients which are controlled products and/or on the Ingredient Disclosure List (Canadian HPA Section 13 & 14).
Polymer of Epichlorohydrin CAS # Proprietary %: Proprietary
Diethlenetriamine CAS # 000111-4-0 %: Proprietary

EXPLANATION OF LABELING REQUIREMENTS, SAFETY PHRASES AND RISK PHRASES:
Xi - Irritant
C - Corrosive

S(1/2): Keep locked up and out of reach of children.
S15: Keep away from heat
S24/25: Avoid contact with skin and eyes
S26: In cause of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27/28: After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of soap and water.
S36/37/39: Wear suitable protective clothing and gloves and eye/face protection.

R22: Harmful if swallowed
R36/37/38: Irritating to eyes, respiratory system and skin
R43: May cause sensitization by skin contact.



The information contained herein is information received from our raw material suppliers and other sources and is believed to be reliable. This data is not to be taken as warranty or representation for which Brunswick assumes legal responsibility.

This Safety Data Sheet complies with EC Commission Directive 2001/58/EC of July 2001