MATERIAL SAFETY DATA SHEET
Discontinued:
Date of Preparation: 08/19/2010
Page 1of 7
SECTION I - Product and Company Description

Product Name: D-234 Contact Adhesive
Product Use: Adhesive in Solvent Solution
Product Number: 11-676047-000

Company: Brunswick
525 W. Laketon
Muskegon, MI 49443

Telephone #: 1/231/725-4972
Emergency #: 1/800/255-3924
CHEMTEL #: 1/800/255-3924
International CHEMTEL #: 1/813/248-0585

SECTION II - Composition/Information on Ingredients
HAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Acetone
Toluene
N-Hexane
Hexane Monomers		67-64-1
108-88-3
110-54-3
Proprietary		NA
NA
NA
Proprietary		Y 40.0
Y 13.0
Y 3.0
Y 44.0
NONHAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.

This product contains no reported carcinogens or suspected carcinogens.
SECTION III - Hazards Identification

DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF INHALED OR SWALLOWED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. Use adequate ventilation. Routes of Entry: Absorbed through the skin. Skin contact. Eye contact. Inhalation. Ingestion POTENTIAL ACUTE HEALTH EFFECTS: Eyes: This product is an eye irritant. Skin: Irritating to the skin. Permeator (absorbed through the skin) Inhalation: Inhalation of the vapors may cause dizziness, headache, nausea, anesthetic effects, loss of consciousness or death. Central nervous system depression. Narcotic effect: may cause nervous system disturbances. Peripheral neuropathy (numbness in limbs). Ingestion: Hamful if swallowed. POTENTIAL CHRONIC HEALTH EFFECTS: Carcinogenic Effects: None Mutagenic: Non-mutagenic Teratogenic Effects: Classified PROVEN for humans (Toluene) Repeated or Prolonged exposure to the substance can cause target organ damage. Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation. TARGET ORGANS: Chronic overexposure may cause arrhythmias (heart beat irregularity) and peripheral nervous system effects. Repeated or prolonged exposure to the substance can produce damage to the kidneys, liver and nervous system. Long-term skin contact to solvents may produce defatting of the skin and dermatitis. Medical Conditions Aggravated: By Overexposure: No additional information. Overexposure Signs and Symptoms: Skin inflammation is characterized by itching, scaling, reddening. Redness, watering, and itching characterize inflammation of the eye
11-676047-000
D-234 Contact Adhesive
MATERIAL SAFETY DATA SHEET
Page 2 of 7
SECTION IV - First Aid Measures

EYE CONTACT: Flush with lukewarm water for 15 minutes. Contact physician.
SKIN CONTACT: Do not remove with solvent. Use waterless hand cleaner followed by soap and water. Remove and clean contaminated clothing.
INHALATION: Remove exposed individual to fresh air. Restore breathing, if necessary. Get medical attention.
INGESTION: Rinse mouth. Call a physician or Poison Control Center immediately. DO NOT induce vomiting unless advised by a physician.
SECTION V - Fire-Fighting Measures

EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam
SPECIAL RISKS: Vapors heavier than air. Development of hazardous combustion gases or vapors possible in the event of fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: Fire Fighters should use self-contained breathing apparatus with face piece.
OTHER INFORMATION: Keep away from sources of ignition. Prevent fire-fighting water from entering surface water or groundwater. Cool Container with spray water from a safe distance. Never use welding or cutting torch on or near container (even empty) because product may ignite explosively.
SECTION VI - Accidental Release Measures

PERSON RELATED PRECAUTIONARY MEASURES: Avoid substance contact. Do not inhale vapors. Ensure fresh air supply in enclosed areas.
ENVIRONMENTAL PROTECTION MEASSURES: Do not allow to enter sewage system, surface or groundwater.
PROCEDURES FOR CLEANING/ABSOPRTION: Use inert absorbent material to take up spilled material. Place in appropriate container until proper disposal method is determined.
SECTION VII - Handling And Storage

NOTES FOR PREVENTION OF FIRE AND EXPLOSION: Keep away from sources of ignition. Use and store this product with adequate ventilation.
NOTES FOR SAFE HANDLING: Avoid generation of vapors. Do not inhale vapors.
STORAGE: Store in well-ventilated area between 40 F (4C) and 100 F (38C). Store away from heat and sources of ignition.
Brunswick takes no responsibility for determining what measures are required for personal protection in any specific application. The general information given should be used with discretion.


11-676047-000
D-234 Contact Adhesive
MATERIAL SAFETY DATA SHEET
Page 3 of 7
SECTION VIII - Exposure Controls/Personal Protection

Hazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Acetone
Toluene
N-Hexane
Hexane Monomers		500 ppm
100 ppm
176 mg/m3
500 ppm		Not established
Not established
Not established
Not established
NonHazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM

PERSONAL PROTECTIVE EQUIPMENT: Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the substances being handled. The resistance of the protective clothing should be ascertained from the respective supplier.

RESPIRATORY PROTECTION: Required when vapors are generated.

EYE PROTECTION: Splash goggles.

HAND PROTECTION: Chemical resistant gloves and skin cream.

INDUSTRIAL HYGIENE: Immediately change any contaminated clothing. Apply skin protective barrier cream. Wash hands and face after handling product. Do not inhale vapors.
SECTION IX - Physical and Chemical Properties

Physical State: Brown syrup-like liquid
Odor: NA
pH: NA
Viscosity:
Lowest Flashpoint: 15 ° F (-9.5 C) (Closed Cup) (Pensky-Martens).
Explosion Level: Lower - 2% Upper - 13%
Vapor Pressure: 185 mm of Hg @ 20 C
Vapor Density: (Air = 1) NA
Weight Per Gallon: lbs./gal.
Solubility: Insoluble in water


11-676047-000
D-234 Contact Adhesive
MATERIAL SAFETY DATA SHEET
Page 4 of 7
SECTION X - Stability and Reactivity

Conditions to be avoided: No additional information
Substances to be avoided: Reactive with acids, alkalis, combustible materials.
Hazardous decomposition products: Products of combustion include: carbon oxides (CO, CO2)
Further information: This product is stable. Hazardous Polymerization will not occur.
SECTION XI - Toxicological Information

Acute Toxicity:


Specific symptoms in animal studies:
Subacute to chronic toxicity:
Bacterial mutagenicity:
Further toxicological information:

Further Data:



11-676047-000
D-234 Contact Adhesive
MATERIAL SAFETY DATA SHEET
Page 5 of 7
SECTION XII - Ecological Information

Biologic degradation: NA

Ecotoxic effects: NA
Biological effects: NA
Fish toxicity: NA
Daphnia toxicity: NA
Maximum permissible toxic concentration: NA
Algeal toxicity: NA
Bacterial toxicity: NA
Protozoa: NA
Further ecological data: Toxicity of the products of Biodegradation: The product of degradation are less toxic than the product itself.
SECTION XIII - Disposal Considerations

Product: Chemicals must be disposed of in accordance with national and local regulations.

Packaging: Packaging must be disposed of in compliance with national and local regulations.


11-676047-000
D-234 Contact Adhesive
MATERIAL SAFETY DATA SHEET
Page 6 of 7
SECTION XIV - Transportation Information

Package Desc: Fiberboard box containing 1 X 3.8 liter steel drum
Weight: 9 #
Dimensions:
Freeze/Thaw stable: N/A
Flashpoint: 15 ° F (-9.5 C) (Closed Cup) (Pensky-Martens).

Land transport:
Classification: ORM-D
Name:

Transport by sea:
Classification: UN1133, Adhesive, 3, II, Ltd. Qty. - up to 5 liters
EMS F-E, S-D
MFAG
Name

Transport by air: Passenger & Cargo aircraft
Classification: UN1133, Adhesive, 3, II
Name:
Packaging Instructions: 305

The transport regulations are cited according to international regulations and in the form applicable in the United States. Possible deviations in other counties are not considered.
THIS TRANSPORT DATA APPLIES TO THE ENTIRE PACKAGE.
SECTION XV - Regulatory Information

Labeling according to Land Transport:
Hazard: ORM-D
Package:
Other: Orientatation Arrows

Labeling according to Sea Transport:
Hazard:
Package: Adhesive, UN1133, Ltd Qty
Other: Orientation Arrows

Labeling according to Air Transport
Hazard: Flammable Liquid
Package: Adhesive, UN1133
Other: Orientation Arrows


11-676047-000
D-234 Contact Adhesive
MATERIAL SAFETY DATA SHEET
Page 7 of 7
SECTION XVI - Other Information

HMIS Tarings: Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: C

U.S. Regulations: All components of this product are listed on the TSCA Inventory.
TSCA 4(a) proposed test rules :Acetone, N-hexane
TSCA 2(a) final test rules: N-haxane
TSCA 8(b) inventory: All ingredients are listed.
TSCA 8(d) H and S data reporting: Toluene: 10/04/92.
TSCA 12(b) one time export: Acetone, N-hexane
SARA 302/304/311/312 extremely hazardous substances: No products were found
SARA 302/304 emergency planning and notification. No products were found
SARA 302/304/311/312 extremely hazardous chemicals: Acetone; Toluene, N-hexane.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found
SARA 313 toxic chemicals notification and release reporting: Acetone; Toluene: 1%; N-hexane: 1%

International Regulation:

EINICS: All components of this product are listed on the European Inventory of Existing Commericial Chemical Substances.

DSCL (EEC) R12: Extremely flammable
R28: Very toxic if swallowed.
R36/38: Irritating to eyes and skin

International Lists:
Australia: Acetone; Toluene; N-hexane
China: Acetone; Toluene
Germany Water Class: Toluene; N-hexane
VCI WGK: Toluene
Korea (TCCL): Acetone

State Lists: Connecticut carcinogen reporting list: Toluene
Pennsylvania RTK: Acetone; Toluene; N-hexane
Florida: Acetone; Toluene; N-hexane
Minnesota: Acetone; Toluene; N-hexane
Massachusetts RTK: Acetone; Toluene; N-hexane
New Jersey: Acetone; Toluene; N-hexane
California Prop 65: This product contains the following ingredients, which the State of California has found to cause cancer, birth defects, or other reproductive harm, which would require a warning under the statute: Toluene.

The information contained herein is information received from our raw material suppliers and other sources and is believed to be reliable. This data is not to be taken as warranty or representation for which Brunswick assumes legal responsibility.

This Safety Data Sheet complies with EC Commission Directive 2001/58/EC of July 2001