MATERIAL SAFETY DATA SHEET
Discontinued:
Date of Preparation: 10/11/2007
Page 1of 7
SECTION I - Product and Company Description

Product Name: DBA Pro-Ject Injection Hardener Component B
Product Use: Epoxy Hardener
Product Number: 111422

Company: DBA Products Company Inc.
525 W. Laketon
Muskegon, Michigan 49441

Telephone #: 1/231/725-4972
Emergency #: 1/800/255-3924
CHEMTEL #: 1/800/255-3924
International CHEMTEL #: 1/813/248-0585

SECTION II - Composition/Information on Ingredients
HAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Aminoethylpiperazine
Alkyl Phenol
Diethylenetriamine
Poloxypropylenediamine		140-31-8
84852-15-3
111-40-0
9046-10-0		9046-10-0Y 17.5
Y 35.0
Y 9.5
Y 29.0
NONHAZARDOUS
INGREDIENT
MATERIAL DESCRIPTION
REF#		CAS#ECN#SARA
313
Y/N
% Wt.
Clays
Silicon Dioxide
Water
Pigment		Proprietary
112945-52-5
7732-18-5
Proprietary		Proprietary
112945-52-5
7732-18-5
Proprietary		N 4.5
N 3.0
N 1.0
N .5

This product contains a chemical reported to be a carcinogen or suspected carcinogen.
SECTION III - Hazards Identification

Emergency Overview: DANGER! CORROSIVE - CAUSES EYE AND SKIN BURNS. HARMFUL OR FATAL IF INHALED OR SWALLOWED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. DO NOT INDUCE VOMITING. PRODUCT IS A LUNG IRRITANT. Use only with adequate ventilation. ROUTE (s) OF ENTRY: Skin contact, Eye contact, Inhalation, Ingestion. POTENTIAL ACUTE HEALTH EFFECTS: EYES: Causes eye irritation, experienced as pain, with excessive blinking and tear production, and seen as extreme redness and swelling of the eye and possible chemical burn of the eye. Severe eye damage may cause blindness. SKIN: Causes severe irritation with pain, severe irritation with pain, severe excess redness with chemical burns, blister formation, and possible tissue destruction. INHALATION: Vapors or mist, especially as generated from heating the material or as from exposure in poorly ventilated areas of confined areas, are irritating and cause nasal discharge, coughing and discomfort in nose and throat. Prolonged or repeated overexposure may result in lung damage. INGESTION: Causes burning of mouth, throat, and stomach with abdominal and chest pain, during swallowing or vomiting, resulting in lung damage. SENSITIZATION: No Data. POTENTIAL CHRONIC HEALTH EFFECTS: Carcinogenic Effects: None known. Mutagenic Effects: None known. Teratogenic Effects: No data. Repeated or prolonged exposure to the substance can produce target organ damage. Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation. TARGET ORGANS: None known.MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: No additional information. OVEREXPOSURE SIGNS AND SYMPTOMS: Skin inflammation is characterized by itching, scaling, reddening. Redness, watering, and itching characterize inflammation of the eye.
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SECTION IV - First Aid Measures

EYE CONTACT: Flush with lukewarm water for 15 minutes. Contact physician.
SKIN CONTACT: Do not remove with solvent. Use waterless hand cleaner followed by soap and water. Remove and clean contaminated clothing.
INHALATION: Remove exposed individual to fresh air. Restore breathing, if necessary. Get medical attention.
INGESTION: Rinse mouth. Call a physician or Poison Control Center immediately. DO NOT induce vomiting unless advised by a physician.
SECTION V - Fire-Fighting Measures

EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam
SPECIAL RISKS: Vapors heavier than air. Development of hazardous combustion gases or vapors possible in the event of fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: Fire Fighters should use self-contained breathing apparatus with face piece.
OTHER INFORMATION: Keep away from sources of ignition. Prevent fire-fighting water from entering surface water or groundwater. Cool Container with spray water from a safe distance. Never use welding or cutting torch on or near container (even empty) because product may ignite explosively.
SECTION VI - Accidental Release Measures

PERSON RELATED PRECAUTIONARY MEASURES: Avoid substance contact. Do not inhale vapors. Ensure fresh air supply in enclosed areas.
ENVIRONMENTAL PROTECTION MEASSURES: Do not allow to enter sewage system, surface or groundwater.
PROCEDURES FOR CLEANING/ABSOPRTION: Use inert absorbent material to take up spilled material. Place in appropriate container until proper disposal method is determined.
SECTION VII - Handling And Storage

NOTES FOR PREVENTION OF FIRE AND EXPLOSION: Keep away from sources of ignition. Use and store this product with adequate ventilation.
NOTES FOR SAFE HANDLING: Avoid generation of vapors. Do not inhale vapors.
STORAGE: Store in well-ventilated area between 40 F (4C) and 100 F (38C). Store away from heat and sources of ignition.
Brunswick takes no responsibility for determining what measures are required for personal protection in any specific application. The general information given should be used with discretion.


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MATERIAL SAFETY DATA SHEET
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SECTION VIII - Exposure Controls/Personal Protection

Hazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Aminoethylpiperazine
Alkyl Phenol
Diethylenetriamine
Poloxypropylenediamine		Not established
Not established
Not established
Not established		Not established
Not established
Not established
Not established
NonHazardous
Component		ACGIH
TLV(TWA)
PPM		OSHA
PEL
PPM
Clays
Silicon Dioxide
Water
Pigment		Not established
Not established
Not established
Not established		Not established
Not established
Not established
Not established

PERSONAL PROTECTIVE EQUIPMENT: Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the substances being handled. The resistance of the protective clothing should be ascertained from the respective supplier.

RESPIRATORY PROTECTION: Required when vapors are generated.

EYE PROTECTION: Splash goggles.

HAND PROTECTION: Chemical resistant gloves and skin cream.

INDUSTRIAL HYGIENE: Immediately change any contaminated clothing. Apply skin protective barrier cream. Wash hands and face after handling product. Do not inhale vapors.
SECTION IX - Physical and Chemical Properties

Physical State: Brown, thickly oily liquid
Odor: Amine, ammonia-like smell
pH: N/A
Viscosity: N/A
Lowest Flashpoint: >210 ° F (100 C).
Explosion Level: Lower - Unknown Upper - Unknown
Vapor Pressure: < 1 mm Hg
Vapor Density: (Air = 1) Greater than 1
Weight Per Gallon: lbs./gal.
Solubility: Negligible ( in H2O )


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MATERIAL SAFETY DATA SHEET
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SECTION X - Stability and Reactivity

Conditions to be avoided: High heat, amines, strong oxidizers, acids and bases
Substances to be avoided: High heat, amines, strong oxidizers, acids and bases
Hazardous decomposition products: Fumes, carbon, dioxide, carbon monoxide, acrid smoke, phenolics, and alcehydes
Further information: Product is stable. Hazardous polymerization will auto-polymerize at very high temperatures.
SECTION XI - Toxicological Information

Acute Toxicity:
N/A

Specific symptoms in animal studies: N/A
Subacute to chronic toxicity: N/A
Bacterial mutagenicity: N/A
Further toxicological information: N/A

Further Data: Product is estimated to be moderately toxic. Chronic effects could include skin sensitization and lung irritation. If swallowed, physician should pump material from stomach. Do not induce vomiting. No known carcinogenicity



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SECTION XII - Ecological Information

Biologic degradation: N/A

Ecotoxic effects: N/A
Biological effects: N/A
Fish toxicity: N/A
Daphnia toxicity: N/A
Maximum permissible toxic concentration: N/A
Algeal toxicity: N/A
Bacterial toxicity: N/A
Protozoa: N/A
Further ecological data: Not determined. Quantities involved in standard packaging suggest negligible impact probable.
SECTION XIII - Disposal Considerations

Product: Chemicals must be disposed of in accordance with national and local regulations.

Packaging: Packaging must be disposed of in compliance with national and local regulations.


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MATERIAL SAFETY DATA SHEET
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SECTION XIV - Transportation Information

Package Desc: 1 Plastic Drum x 5 Gallons (18.9 Litres)
Weight: 40#
Dimensions: 13x13x16 = 1.565
Freeze/Thaw stable: N/A
Flashpoint: >210 ° F (100 C).

Land transport:
Classification: UN3267, Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amines), 8, III
Name:

Transport by sea:
Classification: UN3267, Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amines),8 , III Marine Pollutant (Alkyl Phenol)
EMS F-A, S-B
MFAG
Name

Transport by air: Cargo Aircraft Only
Classification: UN3267, Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amines), 8, III
Name:
Packaging Instructions: 820 - Cargo Aircraft Only

The transport regulations are cited according to international regulations and in the form applicable in the United States. Possible deviations in other counties are not considered.
THIS TRANSPORT DATA APPLIES TO THE ENTIRE PACKAGE.
SECTION XV - Regulatory Information

Labeling according to Land Transport:
Hazard: Corrosive Liquid
Package: Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amines), UN3267
Other: Orientation Arrows

Labeling according to Sea Transport:
Hazard: Corrosive Liquid
Package: Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amines), UN3267
Other: Orientation Arrows - Marine Pollutant

Labeling according to Air Transport
Hazard: Corrosive Liquid
Package: Corrosive Liquid, Basic Organic, N.O.S., (Contains Aliphatic Amines), UN3267
Other: Orientation Arrows - Cargo Aircraft Only


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MATERIAL SAFETY DATA SHEET
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SECTION XVI - Other Information

HMIS Ratings Health: 2 Flammability: 1 Reactivity: 0
NFPA Ratings: Health: 2 Flammability: 1 Reactivity: 0 Other: None

REGULATORY DATA

SARA HAZARD CATEGORIES (311/312): Immediate (Acute) Health Hazard. Delayed (Chronic) Health Hazard.

TOXIC SUBSTANCE CONTROL ACT (TSCA) INVENTORY STATUS: This product, or its components, are listed on or are exempt from the Toxic Substance Control Act (TSCA) Inventory of Chemical Substances.

Class D, Div 1, Subdivision B: Toxic, Class E: Corrosive (estimated)

CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65)
Epichlorohydrin (106-89-8) < 0.0002% CA_65 C/R
Phenyl glycidyl ether (122-60-1) < 0.0006% CA_65 C

CANADIAN INFORMATION: Hazardous Products Act Information: This product contains the following ingredients which are Controlled Products and/or on the Ingredient Disclosure List (Canadian HPA, section 13 and 14).
COMPONENTS CAS NUMBERS %
Nonyl Phenol 84852-15-3 Proprietary
Aminoethylpiperazine 000140-31-8 Proprietary
Diethylenetriamine 000111-40-0 <1
Triethylenetramine 000112-24-3 <1
Aminoethylethanolamine 000111-41-1 <1

WHMIS INFORMATION: The Canadian Workplace Hazardous Materials Communication Standard, 29 CFR 1910.1200.
D1B - Material is toxic with short exposure and moderate dosage.
D2A - Material is tetragenic, embryotoxic, or fetotoxic.
D2A - Respiratory tract sensitizer
D2B - Eye or skin irritant
D2B - Skin sensitizer
E - Corrosive to metal or skin.

CA_65 C/A = the chemical identified with this code is known to the State of California to cause both cancer and birth defects or other reproductive harm.

EXPLANATION OF LABELING REQUIREMENTS, SAFETY PHRASES AND RISK PHRASES

This product contains items, which may require the labeling and risk phrases shown above. The actual product labels and risk phrases may vary. They are warnings particular to the raw materials incorporated into this product. They are listed to inform the user that components in this product may cause these hazardous actions to occur in particular situations.

LABELING::
X - Harmful
Xi - Irritant
Xn - Harmful
N - Dangerous for the environment.
C - Corrosive

SAFETY PHRASES:
S15: Keep away from heat
S24/25: Avoid contact with skin and eyes.
S27/28: After contact with skin, take off immediately all contaminated clothing, an wash immediately with plenty of soap and water.
S37/39: Wear suitable gloves and eye/face protection

RISK PHRASES:
R22: Harmful if swallowed.
R34: Causes burns.
R36/37/38: Irritating to eyes, respiratory system and skin.
R43: May cause sensitization by skin contact.
R50: Very toxic to aquatic organisms.
R53: May cause long-term adverse effects in a aquatic environment.


The information contained herein is information received from our raw material suppliers and other sources and is believed to be reliable. This data is not to be taken as warranty or representation for which Brunswick assumes legal responsibility.

This Safety Data Sheet complies with EC Commission Directive 2001/58/EC of July 2001